Hi Emma,
I can certainly understand your concerns. It is illegal for anyone other than a dentist to prescribe the whitening gel. Theoretically you could achieve the same result if you used tha same materials and took your impression to the same quality as a dentist would.
It would be much better for your to have your dentist whiten your teeth. I would also like to make you aware it is unlikly your NHS dentist could colour match your teeth perfectly on the NHS given the limitations of the loabs they can use. This is not to say you would be unhappy with the results. I hope you can appreciate my thought processes
Kindest regards
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